Solute Descriptors for Phenoxide Anions and Their Use To Establish Correlations of Rates of Reaction of Anions with Iodomethane
نویسندگان
چکیده
منابع مشابه
Solute descriptors for phenoxide anions and their use to establish correlations of rates of reaction of anions with iodomethane.
Partition coefficients from water to organic solvents for phenoxide anions have been obtained using a method based on the variation of pK(a) of phenols with solvent. From these partition coefficients, the Abraham descriptors for phenoxide anions, on the same scale as descriptors for neutral molecules, have been obtained. Equations have been constructed for the prediction of descriptors, and val...
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2010
ISSN: 0022-3263,1520-6904
DOI: 10.1021/jo100292j